一锅法制备纳米纤维素及其性能研究

采用一种操作简单、绿色环保的以对甲苯磺酸为催化剂对竹纤维进行水热处理制备纳米纤维素(NCC)的方法。考察了反应时间、反应温度和超声作用对纳米纤维素得率和性能的影响。结果表明,在反应温度110℃、反应时间45 min、超声时间120 min的条件下,纳米纤维素得率最高。     

电老化后聚丙烯层压纸的绝缘性能变化及局部放电特性

高温超导电缆所用的聚丙烯层压纸(PPLP)为绕包式结构,由于整流器件的存在使其承受交直流复合电压,在对接间隙处易发生局部放电.在长期工作电压下,其绝缘性能会发生变化,同时会对局部放电产生影响.本文在液氮环境下对PPLP进行直流电老化实验,采用内部放电模型来模拟对接间隙,并结合仿真计算分析内部放电模型的电场分布,对电老化机理和局部放电结果进行讨论分析.结果表明:电老化后PPLP的电导率和相对介电常数随老化时间的增加整体呈增大趋势,其直流电气强度随电老化时间的增加逐渐下降,但仍保持良好的绝缘性能.局部放电的剧烈程度随PPLP电老化时间的增加有所增大,局部放电发生的相位主要集中在复合电压的上升阶段,且复合电压中的交直流比例是影响局部放电的主要因素.     

镁质熔剂性球团矿相的多重分形谱

 球团矿相微观结构决定其冶金物理化学性能，为透视球团矿微观结构与其宏观冶金物理化学性能之间的依赖关系，需要解决的首要关键问题是矿相微观视觉特征的提取与定量表征。以镁质熔剂性球团微观矿相为研究对象，在直观分析矿相视觉特征的基础上，采用多重分形谱分析方法，提取矿相的微观多重分形谱定量表征值f（α），并分别深度挖掘由f（α）衍生出的对称度特征值Δf、谱宽特征值Δα、容量维特征值D（0）随碱度变化的迁移规律和随矿相检测位置变化的迁移规律。研究结果表明，矿相微观视觉特征在HSV颜色空间上呈现的颜色特征未在碱度变化和位置变化上存在显著差异性；矿相微观多重分形谱分析中，Δf、Δα、D（0） 3个特征值在碱度变化和位置变化上有显著的差异性，可以很好地表征碱度迁移规律和位置迁移规律。     

Dependence of crystal structure on mechanical and thermophysical properties of magnetoplumbite-type LnMgAl11O19 ceramics with substitution of Ln3+ Ions

Lanthanum hexaaluminate is a promising candidate to establish yttria partially stabilized zirconia as a thermal barrier coating material for super alloy due to their remarkable stability and thermophysical performance. In order to understand the relationship between the structure and properties and gain new low thermal conducting materials, the LnMgAl₁₁O₁₉ (LnMA, Ln: La, Pr, Nd, Sm, Eu, Gd) materials were synthesized firstly and further used to produce the LnMA ceramics. With the increasing relative atomic mass of the replaced Ln³⁺ ions from La to Gd, the lattice parameters and grain sizes of the LnMA platelets decrease, while the mechanical properties increase, and the thermal physic properties decrease. The GdMgAl₁₁O₁₉ ceramics obtain the lowest thermal conductivity with the value of 1.91-1.78 W/m K in the range from room temperature to 800°C, which could be considered as a promising candidate for application in thermal barrier coating materials. These results could further provide reference for developing novel materials lower thermal conductivity.     

Synthesis of a novel DOPO‐based polyphosphoramide with high char yield and its application in flame‐retardant epoxy resins

A novel and highly effective flame retardant (FR), DOPO‐TPMP oligomer, was synthesized by a simple condensation of 4‐(hydroxymethyl)‐2,6,7‐trioxa‐1‐phosphabicyclo[2.2.2]octane‐1‐oxide and phosphorus oxychloride followed by a polycondensation reaction with 6‐(2,5‐dihydroxyphenyl)‐6H‐dibenzo[c,e][1,2]oxaphosphinine‐6‐oxide. The chemical structure of DOPO‐TPMP was well characterized using Fourier transform infrared and NMR spectra. DOPO‐TPMP was used as an additive‐type FR for epoxy resin (EP). The FR properties of the resultant EP composites were investigated by limiting oxygen index (LOI) test, UL‐94 vertical burning test and cone calorimeter measurements. Specifically, the EP composite containing 10.0% DOPO‐TPMP achieved a LOI value of 36.1%, V‐0 rating in the UL‐94 test and a 58% reduction in peak heat release rate. Further mechanism analysis attributed the enhanced flame retardancy to the increased char yield on the addition of DOPO‐TPMP. © 2019 Society of Chemical Industry     

基于近似计算技术的FPRM电路面积优化

近似计算技术通过降低电路输出精度实现电路功耗、面积、速度等方面的优化.本文针对RM（Reed-Muller）逻辑中"异或"运算特点，提出了基于近似计算技术的适合FPRM逻辑的电路面积优化算法，包括基于不相交运算的RM逻辑错误率计算方法，及在错误率约束下，有利于面积优化的近似FPRM函数搜索方法等.优化算法用MCNC（Microelectronics Center of North Carolina）电路进行测试.实验结果表明，提出的算法可以处理输入变量个数为199个的大电路，在平均错误率为5.7%下，平均电路面积减少62.0%，并在实现面积优化的同时有利于实现电路的动态功耗的优化且对电路时延影响不大.     

Sintering mechanism of high-intensity and low-density ceramic proppants prepared by recycling of waste ceramic sands

Waste ceramic sands were effectively used to prepare the high-intensity and low-density ceramic proppants, realising the recycling of the waste ceramic sands. The technology involved the pelletising in an intensive mixer, in which the waste ceramic sands and other starting materials were added, and followed by heat-treatment under different sintering conditions. The sintering temperature, holding time and heating rate were optimised by investigating the crystalline phase, microstructure, density and breakage ratio of the obtained proppants. The results showed that the proppants sintered at 1260°C for 2?h with a heating rate of 5°C?min^–1 under air atmosphere exhibited high crush resistance and low density, with the breakage ratio of 8.5% under 52?MPa closure pressure and bulk density of 1.65?g?cm^–3. The proppants prepared by bauxite, waste ceramic sands and sintering aids are promising candidates as high-intensity and low-density fracturing proppants in future applications.     

基于压缩感知的移动群智感知任务分发机制

针对移动群智感知任务中区域全覆盖感知成本过高问题，提出基于压缩感知的移动群智感知任务分发（CS-TD）机制。首先提出了感知任务整体成本模型，该模型综合考虑了参与感知任务的节点个数、节点的感知次数与数据上传次数；然后基于成本模型，分析感知节点的日常移动轨迹，结合压缩感知数据采集技术，提出了一种基于感知节点轨迹的压缩感知采样方法；其次通过区域全覆盖最少节点（RCLN）算法，选出最佳节点集合，对节点进行任务分配，利用压缩感知技术恢复节点数据；最后在多次感知任务的迭代中对感知节点的可信程度进行评定，保证任务方案的最优性。对CS-TD分发模型进行多次实验验证，与已有的CrowdTasker算法相比，CS-TD算法平均成本降低了30%以上。CS-TD模型能有效降低感知节点的消耗，能在全覆盖感知任务中降低整体感知成本。     

西藏甲玛超大型斑岩成矿系统找矿方向

甲玛矿床位于西藏冈底斯成矿带，其勘查和研究程度均较高，矿体由斑岩型矿体、矽卡岩型矿体、角岩型矿体及外围独立金矿体组成，具有多元矿体结构，其成矿元素为Cu、Mo、Pb、Zn、Au和Ag，呈现多金属成矿作用特征。矿区深部及外围的勘查找矿方向一直是地质学者们关注的热点。在斑岩成矿系统理论的指导下，近年来在甲玛矿区深部及外围取得了重大找矿突破。基于最新勘查成果，甲玛矿床共探获铜资源储量超过850×10⁴ t，钼资源量达91×10⁴ t，铅锌资源量超过150×10⁴ t，伴生金储量为220 t，伴生银储量超过1×10⁴ t，达到超大型矿床规模。为进一步指导区域及外围勘查找矿工作，以甲玛矿区最新勘查成果为基础，通过对矿区钻孔的详细编录，采用地表构造蚀变填图等方法，系统解剖了甲玛矿区不同矿段的矿体地质结构，并揭示了其矿床地质特征。结合甲玛矿区新发现的主矿段深部的厚大矽卡岩矿体和外围则古朗北矿段的巨厚斑岩型矿体，分析了矿区深部及外围找矿潜力，认为甲玛矿区深部仍存在厚大矽卡岩铜钼矿体和斑岩钼矿体，应进一步加强对外围则古朗北矿段新发现的斑岩矿体、矽卡岩矿体和角岩型矿体的勘查，建立新的资源储备。此外，归纳总结有效勘查找矿方法，以期为深入探究甲玛矿床成矿作用和创建综合勘查找矿模型提供参考依据，并通过系统梳理矿区已有勘查和研究资料，总结甲玛矿床的找矿标志，为区域类似矿床的地质勘查提供重要线索，也为青藏高原斑岩成矿系统的勘查和研究工作奠定坚实基础。